Mn(III)-mediated phosphonation-azidation of alkenes: a facile synthesis of beta-azidophosphonates
Mn(III)-mediated phosphonation-azidation of alkenes: a facile synthesis of beta-azidophosphonates
复制标题
Mn(III) 介导的烯烃磷酸化-叠氮化反应：β-叠氮膦酸酯的简便合成
DOI：
10.1039/c5cc03995a
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发表时间：
2015
影响因子：
4.9
通讯作者：
Zhao Yufen
中科院分区：
文献类型：
--
作者：
Xu Jian;Li Xueqin;Gao Yuzhen;Zhang Liangliang;Chen Weizhu;Fang Hua;Tang Guo;Zhao Yufen
通过Mn（OAc）3介导的烯烃自由基氧化膦酸-叠氮化反应，实现了一种合成β-叠氮膦酸酯的新方法。P（O）-H化合物、烯烃和叠氮基三甲基硅烷的起始原料稳定且廉价。这种方法可以很容易地适用于大规模制备。
A new and general method for the synthesis of β-azidophosphonates has been achieved through Mn(OAc)3-mediated radical oxidative phosphonation–azidation of alkenes. The starting materials of P(O)–H compounds, alkenes, and azidotrimethylsilane are stable and cheap. This method can be easily adapted for large-scale preparation.