Ultrasonic Effects on Electroorganic Processes.^ Product-selectivity in Electroreduction of Benzaldehydes
Ultrasonic Effects on Electroorganic Processes.^ Product-selectivity in Electroreduction of Benzaldehydes
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超声波对有机电过程的影响。^ 苯甲醛电还原中的产物选择性
DOI：
10.1246/cl.1994.1619
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发表时间：
1994
影响因子：
1.6
通讯作者：
T. Nonaka
中科院分区：
文献类型：
--
作者：
K. Matsuda;M. Atobe;T. Nonaka
超声波辐射对有机电催化体系中苯甲醛等的还原反应的产物选择性有显著影响。通过照射，通过消耗较少的电子形成的还原产物的选择性急剧增强。这些影响被合理化，因为不是由于空化，而是由于超声波对电解质溶液的搅拌。
Ultrasonic irradiation to electroorganic systems resulted in significant effects on product-selectivity in the reduction of benzaldehydes and others. By the irradiation, the selectivity of reduction products formed by consuming fewer electrons was drastically enhanced. The effects were rationalized as due to not cavitation but agitation of electrolytic solutions by ultrasonic waves.