ESR Study of Copper(II) and Silver(II) Tetraphenylporphyrin
ESR Study of Copper(II) and Silver(II) Tetraphenylporphyrin
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四苯基卟啉铜(II)和银(II)的ESR研究
DOI：
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发表时间：
1969
期刊：
影响因子：
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通讯作者：
M. T. Rogers
中科院分区：
文献类型：
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作者：
P. Manoharan;M. T. Rogers
用纯固体材料、溶液、磁稀释单晶和多晶粉末对铜(II)四苯基卟啉和银(II)四苯基卟啉进行了ESR波谱研究。已经有可能获得相当完整的ESR数据，包括14N、63‘65Cu和107’109Ag的超精细相互作用张量。这些结果已被用来估算这些化合物的分子轨道系数，并讨论了化学键的细节。
Copper(II) tetraphenylporphyrin and silver(II) tetraphenylporphyrin have been studied by ESR spectroscopy using the pure solid materials, solutions, magnetically-diluted single crystals, and polycrystalline powders. It has been possible to obtain rather complete ESR data, including the hyperfine interaction tensors, for 14N, 63’65Cu, and 107’109Ag. The results have been used to estimate molecular orbital coefficients in these compounds and to discuss details of the chemical bonding.