Topological polymer chemistry: a cyclic approach toward novel polymer properties and functions
Topological polymer chemistry: a cyclic approach toward novel polymer properties and functions
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DOI：
10.1039/c1py00088h
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发表时间：
2011-08
影响因子：
4.6
通讯作者：
Takuya Yamamoto;Y. Tezuka
中科院分区：
文献类型：
--
作者：
Takuya Yamamoto;Y. Tezuka
概述了拓扑聚合物化学的最新进展，特别强调具有程序化化学结构的单环（环）和多环聚合物，现在通过新开发的合成方案可以获得保证纯度的聚合物。通过使用这些拓扑聚合物，现在已经实现了前所未有的机会，可以为溶液或体块，静态或动态状态，或自组装的基本聚合物特性提供新的见解。此外，聚合物材料的不寻常的性质和功能，现在已经揭示了基于它们的循环拓扑，即拓扑效应，无法实现的线性或分支对偶。
Recent progress observed in Topological Polymer Chemistry is outlined with particular emphasis on single-cyclic (ring) and multi-cyclic polymers having programmed chemical structures, now becoming obtainable with guaranteed purity by newly developed synthetic protocols. By making use of these topological polymers, unprecedented opportunities have now been realized to provide new insights on fundamental polymer properties either in solution or bulk, in static or dynamic states, or in self-assemblies. Moreover, unusual properties and functions for polymer materials have now been revealed based on their cyclic topologies, i.e., topology effects, unattainable either by linear or branched counterparts.