Photopolymerization without light polymerization of acrylates using oxalate esters and hydrogen peroxide
Photopolymerization without light polymerization of acrylates using oxalate esters and hydrogen peroxide
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DOI：
10.1021/ma060905i
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发表时间：
2006-08-22
期刊：
影响因子：
5.5
通讯作者：
Fedorov, Andrei V.
中科院分区：
文献类型：
--
作者：
Ermoshkin, Andrey A.;Neckers, Douglas C.;Fedorov, Andrei V.
We define the photopolymerization of acrylates without light as a process wherein the radical chain polymerization produced by photoinitiators are produced by nonphotochemical means. We use the chemical reactions of the chemiluminescent lightstick to accomplish this. An important potential application is in producing "photopolymers" in areas that are not light accessible as in the inside of a tube or behind a pipe. Polymerizable acrylate mixtures containing dissolved oxalate esters undergo radical chain polymerization when exposed to a flow of nitrogen gas saturated with hydrogen peroxide vapors. We propose aryloxyoxalyl hydroperoxides to be the reactive species.
