Diagnosing current distributions in batteries with magnetic resonance imaging

Diagnosing current distributions in batteries with magnetic resonance imaging
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DOI:
10.1016/j.jmr.2019.106601
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发表时间:
2019-12-01
影响因子:
2.2
通讯作者:
Jerschow, Alexej
Jerschow, Alexej
中科院分区:
化学3区
文献类型:
--
作者:
Mohammadi, Mohaddese;Silletta, Emilia, V;Jerschow, Alexej

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Batteries and their defects are notoriously difficult to analyze non-destructively, and consequently, many defects and failures remain little noticed and characterized until they cause grave damage. The measurement of the current density distributions inside a battery could reveal information about deviations from ideal cell behavior, and could thus provide early signs of deterioration or failures. Here, we describe methodology for fast nondestructive assessment and visualization of the effects of current distributions inside Li-ion pouch cells. The technique, based on magnetic resonance imaging (MRI), allows measuring magnetic field maps during charging/discharging. Marked changes in the distributions are observed as a function of the state of charge, and also upon sustaining damage. In particular, it is shown that nonlinearities and asymmetries of current distributions could be mapped at different charge states. Furthermore, hotspots of current flow are also shown to correlate with hotspots in charge storage. This technique could potentially be of great utility in diagnosing the health of cells and their behavior under different charging or environmental conditions. (C) 2019 Elsevier Inc. All rights reserved.