Non-chelate noncovalent bonding of copper atoms on the nitrogen containing sites of hydrogenated diamond surface
Non-chelate noncovalent bonding of copper atoms on the nitrogen containing sites of hydrogenated diamond surface
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氢化金刚石表面含氮位点上铜原子的非螯合非共价键合
DOI：
10.1016/j.mencom.2019.07.033
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发表时间：
2019
期刊：
影响因子：
--
通讯作者：
K. Takai
中科院分区：
文献类型：
--
作者：
V. Osipov;D. Boukhvalov;K. Takai
我们证明了孤立的铜原子可以结合到完全由氢原子终止的金刚石晶格的四配位表面氮位上。这种成键与表面氮位将未配对的电子(来自反键轨道)提供给第三外星表面试剂的能力有关。
We demonstrate that isolated copper atoms can be bound to the four-coordinated surface nitrogen sites of a diamond lattice fully terminated by atomic hydrogen. This bonding is related to the ability of surface nitrogen sites to donate unpaired electrons (from an antibonding orbital) to third alien surface agents.