Microstructure and ablation resistance of carbon/carbon composites with a zirconium carbide rich surface layer

Microstructure and ablation resistance of carbon/carbon composites with a zirconium carbide rich surface layer
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富含碳化锆表面层的碳/碳复合材料的微观结构和耐烧蚀性能

DOI:
10.1016/j.corsci.2014.04.013
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发表时间:
2014-08
期刊:
影响因子:
8.3
通讯作者:
Hejun Li
Hejun Li
中科院分区:
材料科学1区
文献类型:
--
作者:
Cuiyan Li;Kezhi Li;Hejun Li

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在碳/碳(C/C)复合材料表面制备了厚度为80-100 μm的富碳化锆(ZrC)层。富ZrC层由均匀分散在碳基体中的亚微米ZrC颗粒组成。具有富ZrC层的复合材料的质量烧蚀率比裸C/C复合材料的质量烧蚀率低69%。富ZrC层可以封闭表面孔隙和裂纹,抑制缺陷区的择优烧蚀,并形成连续熔化的ZrO 2层,防止烧蚀过程中碳的氧化。富ZrC层的强化可以减少复合材料的机械剥蚀。
Zirconium carbide (ZrC) rich surface layer with a thickness of 80–100 μm was prepared on carbon/carbon (C/C) composites. The ZrC-rich layer consisted of submicron ZrC particles, homogeneously dispersed in the carbon matrix. The mass ablation rate of the composite with the ZrC-rich layer was 69% lower than that of the bare C/C composites. The ZrC-rich layer could seal the surface pores and cracks to restrain the preferential ablation in the defect area and form a continuously melting ZrO2layer to prevent the carbon from oxidizing during ablation. The strengthened ZrC-rich layer could reduce the mechanical denudation of the composites.
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