Stereoselective synthesis of cis- and trans-2,3-disubstituted eight-membered medium-ring ethers based on Ireland-Claisen rearrangement of 3-alkoxy-2-propenyl glycolate esters and ring-closing olefin metathesis
Stereoselective synthesis of cis- and trans-2,3-disubstituted eight-membered medium-ring ethers based on Ireland-Claisen rearrangement of 3-alkoxy-2-propenyl glycolate esters and ring-closing olefin metathesis
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DOI：
10.1016/j.tetlet.2005.03.114
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发表时间：
2005-05-16
影响因子：
1.8
通讯作者：
Suzuki, T
中科院分区：
文献类型：
--
作者：
Fujiwara, K;Goto, A;Suzuki, T
基于3-烷氧基-2-丙烯基乙醇酸酯的几何选择性合成、乙醇酸酯的Ireland-Claisen重排反应和烯烃复分解反应，发展了一种简单的顺式和反式2，3-二取代中型环醚的立体选择性合成方法。(c)2005爱思唯尔有限公司保留所有权利。
A simple stereoselective synthesis of cis- and trans-2,3-disubstituted medium-sized cyclic ethers has been developed based on geometry-selective synthesis of 3-alkoxy-2-propenyl glycolate esters, Ireland-Claisen rearrangement of the glycolate esters, and ring-closing olefin metathesis. (c) 2005 Elsevier Ltd. All rights reserved.