The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators

The role of charge in 1,2,3-triazol(ium)-based halogen bonding activators
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DOI:
10.1039/c8cc00527c
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发表时间:
2018-04-18
影响因子:
4.9
通讯作者:
Huber, Stefan M.
Huber, Stefan M.
中科院分区:
化学2区
文献类型:
--
作者:
Dreger, Alexander;Engelage, Elric;Huber, Stefan M.

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研究了电荷对单阳离子和阳离子三氮唑卤键给体性能的影响。除了卤化物提取基准反应中的活性外,还通过X射线结构分析和等温滴定量热法对卤素成键进行了评估。
The influence of charge on the performance of monocationic and dicationic triazol(ium)-based halogen bond donors was investigated. Next to the activity in a halide abstraction benchmark reaction, halogen bonding was also evaluated via X-ray structural analyses and isothermal titration calorimetry.