Catalytic chromium reduction using formic acid and metal nanoparticles immobilized in a metal-organic framework.

Catalytic chromium reduction using formic acid and metal nanoparticles immobilized in a metal-organic framework.
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DOI:
10.1039/c3cc00293d
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发表时间:
2013-03
影响因子:
4.9
通讯作者:
M. Yadav;Qiang Xu
M. Yadav;Qiang Xu
中科院分区:
化学2区
文献类型:
--
作者:
M. Yadav;Qiang Xu

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采用双溶剂法将高度分散的金属纳米颗粒固定在金属有机骨架 (MOF) MIL-101 的孔中。研究了所得复合材料使用甲酸将 Cr(VI) 还原为 Cr(III) 的过程,结果表明 Pt 和 Pd 催化剂具有活性,固定在 MOF 中的 Pt 纳米颗粒表现出最佳性能。
Highly dispersed metal nanoparticles were immobilized in the pores of a metal-organic framework (MOF), MIL-101, using a double solvents method. The resulting composites were investigated in the reduction of Cr(VI) to Cr(III) using formic acid, showing that the Pt and Pd catalysts were active with the Pt nanoparticles immobilized in MOF exhibiting the best performance.