The organocatalytic vinylogous aldol reaction: recent advances.
The organocatalytic vinylogous aldol reaction: recent advances.
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DOI：
10.1002/chem.201101269
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发表时间：
2011-08
期刊：
影响因子：
--
通讯作者：
S. Pansare;E. Paul
中科院分区：
文献类型：
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作者：
S. Pansare;E. Paul
在过去的十年中，有机催化已经成为在非常温和的条件下立体选择性形成碳-碳键的有力工具。大量传统合成转化的有机催化版本现在已经很好地建立，并且对有机催化的基本概念的新应用的探索仍在继续。本文综述了有机催化乙烯基醇醛缩合反应的研究进展。虽然在这一领域取得了显著进展，但仍面临重大挑战。
Over the past decade, organocatalysis has emerged as a powerful tool for stereoselective carbon-carbon bond formation under exceptionally mild conditions. The organocatalytic versions of a large number of traditional synthetic transformations are now well established and the quest for new applications of the basic concepts of organocatalysis continues. This review addresses the emergent interest in the organocatalytic vinylogous aldol reaction. While noteworthy progress has been made in this area, significant challenges lie ahead.