Thermal properties of AlH3-etherate and its desolvation reaction into AlH3
Thermal properties of AlH3-etherate and its desolvation reaction into AlH3
复制标题
AlH3-醚合物的热性质及其去溶剂化反应生成AlH3
DOI：
10.1016/j.jallcom.2007.03.105
复制
发表时间：
2007
影响因子：
6.2
通讯作者：
C. Jensen
中科院分区：
文献类型：
--
作者：
T. Kato;Y. Nakamori;S. Orimo;C. Brown;C. Jensen
实验研究了乙醛醚酸盐的热性质及其在加热和等温过程中的脱溶反应。在加热过程中，alh3 -酯被分解成γ- alh3，并立即转化为α- alh3。等温过程下的结果通过抑制脱氢反应生成金属Al的发生，为有效获得α-和γ- alh3提供了适宜的条件。
Thermal properties of AlH3-etherate and its desolvation reaction into AlH3were experimentally investigated under heating and isothermal processes. AlH3-ehterate was desolvated to γ-AlH3which immediately transformed into α-AlH3in the heating process. The results under the isothermal process provide appropriate conditions to effectively obtain α- and γ-AlH3by restraining the occurrence of the dehydriding reaction into metallic Al.