4-Homoadamantyl cation. II. Mechanistic studies on Lewis acid catalyzed conversion of homoadamantene to 2-methyladamantane by carbon-13 labeling techniques. Convenient synthesis of 4-homoadamantanone-5-13C and homoadamantene-4-13C
4-Homoadamantyl cation. II. Mechanistic studies on Lewis acid catalyzed conversion of homoadamantene to 2-methyladamantane by carbon-13 labeling techniques. Convenient synthesis of 4-homoadamantanone-5-13C and homoadamantene-4-13C
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4-高金刚烷基阳离子。
DOI：
10.1021/jo00913a033
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发表时间：
1975
期刊：
影响因子：
--
通讯作者：
E. Pretsch
中科院分区：
文献类型：
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作者：
K. Mlinaric;Z. Majerski;E. Pretsch
(20)G. Zwelfel和H. C.布朗，有机反应，13，1（1963）。(21)该化合物在Golay VPC上仅显示一个峰。然而，根据怀尔德等人22关于内-双环戊二烯的氧汞化的结果，该化合物可能是三环[5.2]的8和9种衍生物的混合物。2.02 i 6]十一碳-3-烯（9）。(22)小P.怀尔德，A. R.小波蒂斯G. W. Wright和JM Shepherd，J. Org. Chem.，39，1636（1974）。
(20) G. Zwelfel and H. C. Brown, Org. React., 13, 1 (1963).(21) The compound showed only one peak on Golay VPC. However, In view of the result of Wilder et al. 22 on the oxymercuration of endo-dlcyclopentadiene, the compound would probably be a mixture of 8 and 9 de-rivatives of trlcydo [5.2. 2.02 i6] undec-3-ene (9).(22) P. Wilder, Jr., A. R. Portis, Jr., G. W. Wright, and JM Shepherd, J. Org. Chem., 39, 1636 (1974).