Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes

Controlling the variation of axial water exchange rates in macrocyclic lanthanide(III) complexes
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DOI:
10.1039/b202862j
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发表时间:
2002-01-01
影响因子:
4.9
通讯作者:
Puschmann, H
Puschmann, H
中科院分区:
化学2区
文献类型:
--
作者:
Aime, S;Barge, A;Puschmann, H

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轴向水交换率在定义明确的系列镧系元素配合物取决于第二球水合的程度,这是由复杂的疏水性和性质的镧系元素离子和它的抗衡离子。
The rate of axial water exchange in well-defined series of lanthanide complexes depends on the extent of second sphere hydration which is determined by complex hydrophobicity and the nature of the lanthanide ion and its counter-ion.