Formal C--H insertion of diketocarbene generated by rhodium(II)-catalyzed decomposition of diazodimedone into a benzene molecule
Formal C--H insertion of diketocarbene generated by rhodium(II)-catalyzed decomposition of diazodimedone into a benzene molecule
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DOI：
10.1007/bf01434000
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发表时间：
1996-02-01
影响因子：
1.7
通讯作者：
Ibata, T
中科院分区：
文献类型：
--
作者：
Chapyshev, SV;Nakano, H;Ibata, T
醋酸铑催化重氮二甲酮分解生成的二酮卡宾与苯在室温下反应生成5，5-二甲基-2-苯基-1，3-环己烷二酮，收率88%。
Diketocarbene generated by rhodium(II) acetate-catalyzed decomposition of diazodimedone reacts with benzene at room temperature to give 5,5-dimethyl-2-phenylcyclohexane-1,3-dione in 88% yield.