Microwave-assisted syntheses of highly CO2-selective organic cage frameworks (OCFs)
Microwave-assisted syntheses of highly CO2-selective organic cage frameworks (OCFs)
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DOI：
10.1039/c1sc00589h
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发表时间：
2012-01-01
期刊：
影响因子：
8.4
通讯作者：
Zhang, Wei
中科院分区：
文献类型：
--
作者：
Jin, Yinghua;Voss, Bret A.;Zhang, Wei
采用微波辅助Sonogashira偶联法，将三维分子笼结构单元与不同的二乙炔连接基偶联，成功合成了一系列有机笼状骨架。这些新型骨架材料在环境条件下表现出前所未有的高选择性（高达213/1）。
A series of organic cage frameworks (OCFs) were successfully synthesized through microwave-assisted Sonogashira coupling of 3-D molecular cage building blocks with various diacetylene linkers. These novel framework materials exhibited unprecedented, high ideal selectivity (up to 213/1) in adsorption of CO2 over N-2 under ambient conditions.