Palladium-catalyzed dehydroarylation of triarylmethanols and their coupling with unsaturated compounds accompanied by C-C bond cleavage.
Palladium-catalyzed dehydroarylation of triarylmethanols and their coupling with unsaturated compounds accompanied by C-C bond cleavage.
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DOI：
10.1021/jo049031t
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发表时间：
2004-09
期刊：
影响因子：
--
通讯作者：
Y. Terao;M. Nomoto;T. Satoh;M. Miura;M. Nomura
中科院分区：
文献类型：
--
作者：
Y. Terao;M. Nomoto;T. Satoh;M. Miura;M. Nomura
选择合适的钯催化体系，如Pd(OAc)2-P(1-Nap)3(1-Nap=1-萘基)分别生成相应的芳烃和氢芳化产物，并与二芳基酮反应，三芳基甲醇可有效地脱氢芳基化并与一些不饱和化合物反应。
Triarylmethanols are effectively dehydroarylated and reacted with some unsaturated compounds by using an appropriate palladium catalyst system such as Pd(OAc)2-P(1-Nap)3 (1-Nap = 1-naphthyl) to give the corresponding arenes and hydroarylation products, respectively, along with diaryl ketones.