Isotope Effects in Optical Rotation1
Isotope Effects in Optical Rotation1
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旋光性中的同位素效应1
DOI：
10.1021/ja00962a010
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发表时间：
1966
期刊：
影响因子：
--
通讯作者：
H. F. Hameka
中科院分区：
文献类型：
--
作者：
N. V. Cohan;H. F. Hameka
目前对偶极子弛豫的处理是由于需要预测聚合物液体中小分子和分子段的旋转和扩散速率的方法，其中宏观粘度作为相关参数显然没有意义。新方法在处理Nujol溶剂方面的成功，预示着其在预期领域的适用性。
Conclusions The present treatment of the dipole relaxation was motivated by the need for methods to predict therota-tion and diffusion rates for small molecules and mole-cule segments in polymericliquids, where macroscopic viscosity is obviously meaningless as a correlating parameter. The success of the new correlation in handling Nujol solvent augurs well for its applicability in the intended field.