Metal-Ion Exchange, Small-Molecule Sensing, Selective Dye Adsorption, and Reversible Iodine Uptake of Three Coordination Polymers Constructed by a New Resorcin[4]arene-Based Tetracarboxylate
Metal-Ion Exchange, Small-Molecule Sensing, Selective Dye Adsorption, and Reversible Iodine Uptake of Three Coordination Polymers Constructed by a New Resorcin[4]arene-Based Tetracarboxylate
复制标题
新型间苯二酚[4]芳烃基四羧酸酯构建的三配位聚合物的金属离子交换、小分子传感、选择性染料吸附和可逆碘吸收
DOI：
10.1021/ic502686b
复制
发表时间：
2015-02-16
影响因子：
4.6
通讯作者：
Ma, Jian-Fang
中科院分区：
文献类型：
--
作者：
Lv, Li-Li;Yang, Jin;Ma, Jian-Fang
通过使用新的异种[4]基于芳烃的四羧酸盐，三个功能协调聚合物（CPS），即[（CH3）（2）NH2] [CD2NAL（HCOO）（HCOO）（HCOOH）（HCOOH）（H2O）（H2O）。 ），[（CH3）（2）NH2]（2）[CDL] .CH3OH.4H2O（2）和[（CH3）（2）NH2] [ZN2NA3L2（H2O）（2）]。H2O（3） - 在溶不能进行的条件下合成（H4L = H4L = 2,8,14,20-tetra-pentyl-4,10,16,22-Tetrakis（（4-羧基苯基）氧）-6,12,18,24-tetra-tetra-------------------------18,24-TETRA-甲氧基 - 抗激素[4] Arene和dmf = = n，n'-二甲基甲酰胺）。通过单晶X射线衍射分析证实了1-3的结构，并进一步进行了物理表征。在1中，L和HCOO链接CD（II）和Na（i）离子产生了不寻常的三维（3D）4连接的异质框架（4（4（2）.6（4））（4.8（4.8（3））。 10.12）拓扑。在2中，L阴离子链接Cd（ii）离子给出3D双二极化4连接的框架，并具有（4（2）.6（3）.8）.8）（2）拓扑。在3中，相邻的十二核异质簇通过l阴离子连接在一起，产生二维（2d）（3,8）连接（3.4（2））（3（4）.4（6）.5（6）.5（6） .6（8）.7（3）.8）网络。最引人注目的是，CPS 1和2显示了异常的金属离子交换字符。 CP 2显示了I-2分子的显着可逆adsoption。此外，CPS 1-3可以选择性吸附有机染料，并在小分子中具有高发光的感测特性。
By using a new resorcin[4]arene-based tetracarboxylate, three functional coordination polymers (CPs)namely, [(CH3)(2)NH2][Cd2NaL(HCOO)(2)(HCOOH)(H2O)].H2O (1), [(CH3)(2)NH2](2)[CdL].CH3OH.4H2O (2), and [(CH3)(2)NH2][Zn2Na3L2(H2O)(2)].H2O (3)-have been synthesized under solvothermal conditions (H4L = 2,8,14,20-tetra-pentyl-4,10,16,22-tetrakis((4-carboxybenzyl)oxy)-6,12,18,24-tetra-methoxy-resorcin[4]arene and DMF = N,N'-dimethylformamide). The structures of 1-3 have been confirmed by single-crystal X-ray diffraction analyses and further physically characterized. In 1, L and HCOO link Cd(II) and Na(I) ions to yield an unusual three-dimensional (3D) 4-connected heterometallic framework with (4(2).6(4))(4.8(3).10.12) topology. In 2, L anions link Cd(II) ions to give a 3D binodal 4-connected framework with (4(2).6(3).8)(2) topology. In 3, adjacent dodecanuclear heterometallic clusters are joined together by L anions, yielding a two-dimensional (2D) (3,8)-connected (3.4(2))(3(4).4(6).5(6).6(8).7(3).8) network. Most strikingly, CPs 1 and 2 display unusual metal-ion exchange characters. CP 2 shows remarkable reversible adsoption of I-2 molecules. In addition, CPs 1-3 can selectively adsorb organic dyes and exhibit highly luminescent sensing properties for small molecules.