A chiral tetragonal magnesium-carboxylate framework with nanotubular channels.

A chiral tetragonal magnesium-carboxylate framework with nanotubular channels.
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DOI:
10.1039/c1cc14836b
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发表时间:
2011-10
影响因子:
4.9
通讯作者:
Q. Lin;Tao Wu;Shoutian Zheng;X. Bu;P. Feng
Q. Lin;Tao Wu;Shoutian Zheng;X. Bu;P. Feng
中科院分区:
化学2区
文献类型:
--
作者:
Q. Lin;Tao Wu;Shoutian Zheng;X. Bu;P. Feng

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报道了一种由4(1)(或4(3))螺旋链构成的具有纳米管通道的高度对称的手性镁基MOF(CPF-1)的罕见例子。它具有很高的气体吸附容量(77K,1atm,约1.29wt%H(2);273K,1atm,CO(2)84 cm(3)g(-1))。
Reported here is a rare example of a highly symmetrical chiral Mg-based MOF (CPF-1) with nanotubular channels, built from 4(1) (or 4(3)) helical chains. It exhibits a high gas sorption capacity (ca. 1.29 wt% H(2) at 77 K, 1 atm; 84 cm(3) g(-1) of CO(2) at 273 K, 1 atm).