A chiral tetragonal magnesium-carboxylate framework with nanotubular channels.
A chiral tetragonal magnesium-carboxylate framework with nanotubular channels.
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DOI:
10.1039/c1cc14836b
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发表时间:
2011-10
影响因子:
4.9
通讯作者:
Q. Lin;Tao Wu;Shoutian Zheng;X. Bu;P. Feng
中科院分区:
文献类型:
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作者:
Q. Lin;Tao Wu;Shoutian Zheng;X. Bu;P. Feng
Reported here is a rare example of a highly symmetrical chiral Mg-based MOF (CPF-1) with nanotubular channels, built from 4(1) (or 4(3)) helical chains. It exhibits a high gas sorption capacity (ca. 1.29 wt% H(2) at 77 K, 1 atm; 84 cm(3) g(-1) of CO(2) at 273 K, 1 atm).