Lanthanide luminescent anion sensing:: evidence of multiple anion recognition through hydrogen bonding and metal ion coordination
Lanthanide luminescent anion sensing:: evidence of multiple anion recognition through hydrogen bonding and metal ion coordination
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DOI：
10.1039/b705560a
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发表时间：
2007-01-01
影响因子：
4.9
通讯作者：
Gunnlaugsson, Thorfinnur
中科院分区：
文献类型：
--
作者：
dos Santos, Cidalia M. G.;Fernandez, Pablo Barrio;Gunnlaugsson, Thorfinnur
在CH3CN中感应到磷酸二氢（H2PO4-）后，铽[Tb(III)]二酰基尿素配合物1中心点Tb的延迟镧系发光显著增强，这是通过氢键相互作用和潜在金属离子与Tb（III）配位的多重阴离子结合发生的。
The delayed lanthanide luminescence of the terbium [Tb(III)] diaryl-urea complex 1 center dot Tb is significantly enhanced upon sensing of dihydrogenphosphate ( H2PO4-) in CH3CN, which occurs through multiple anion binding through hydrogen bonding interactions and potential metal ion coordination to Tb(III).