Recent progress of phosphorus composite anodes for sodium/potassium ion batteries
Recent progress of phosphorus composite anodes for sodium/potassium ion batteries
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钠钾离子电池磷复合负极研究进展
DOI：
10.1016/j.ensm.2020.10.003
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发表时间：
2021-01-01
影响因子：
20.4
通讯作者：
Li, Li
中科院分区：
文献类型：
--
作者：
Wang, Ying;Niu, Ping;Li, Li
开发高效储能技术，为可再生能源和可持续能源的利用提供有力支撑，具有重要意义。钠离子电池（SIBs）和钾离子电池（KIBs）作为新一代金属离子电池，由于Na和k丰富的自然储量和成本效益的优点而受到广泛关注。磷在各种负极材料中被视为很有前途的候选材料，但其循环稳定性差，体积变化大导致的电化学反应动力学缓慢以及固有的低电子电导率极大地限制了其在能源方面的实际应用存储设备。通过引入合适的第二组件进行组合已被提议作为潜在解决这些问题的有效策略。本文综述了SIBs/KIBs用磷复合阳极的研究进展。首先总结了阳极材料的主要调制方法，介绍了红/黑磷（RP/BP）对sib / kib的工作机理。然后分别从碳质、金属和有机聚合物基底对RP和BP的合成策略和材料进行了综述。最后介绍了RP/BP复合材料在sib / kib储能系统发展中的挑战和机遇，希望为先进sib / kib储能系统的设计和制造提供一些启示。
Developing highly efficient energy storage technologies is of great significance as the strong support for the utilization of renewable and sustainable energy. Sodium-ion batteries (SIBs) and potassium-ion batteries (KIBs) have attracted considerable attentions as the new generation metal-ion batteries due to the abundance natural reserve and cost-effective merits of Na and K. Phosphorus is viewed as a promising candidate among various anode materials while its poor cycling stability and sluggish electrochemical reaction dynamics caused by huge volume variation and inherently low electronic conductivity greatly limit its practical use for energy storage devices. Compositing by introducing a suitable second component has been proposed as an effective strategy to potentially resolve those issues. Herein, the research progress of phosphorus composite anodes for SIBs/KIBs is reviewed. We firstly summarized the primary modulation methods of anode materials with the working mechanisms of red/black phosphorus (RP/BP) for SIBs/KIBs introduced. The compositing strategies and materials were then reviewed for RP and BP separately from carbonaceous, metallic and organic polymer substrates, respectively. Finally, the challenges and opportunities of RP/BP composites in the development of SIBs/KIBs were presented with the hope to provide some inspirations for the design and fabrication of advanced SIBs/KIBs energy storage systems.