Generation of a dynamic system of three-dimensional tetrahedral polycatenanes.
Generation of a dynamic system of three-dimensional tetrahedral polycatenanes.
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DOI：
10.1002/anie.201209708
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发表时间：
2013-05-27
期刊：
影响因子：
--
通讯作者：
Sanders JK
中科院分区：
文献类型：
--
作者：
Black SP;Stefankiewicz AR;Smulders MM;Sattler D;Schalley CA;Nitschke JR;Sanders JK
通过配体（含缺电子的萘二亚胺核）和富电子的芳冠醚1,5 -萘二亚胺[38]冠- 10配体构建的动态Fe4L6四面体笼，制备了聚catenated四面体的动态组合文库。文库中最高阶的种是四面体[7]链烷。
Seven of the best: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic Fe4L6 tetrahedral cage, constructed from ligands containing an electron‐deficient naphthalenediimide core, and an electron‐rich aromatic crown ether, 1,5‐dinaphtho[38]crown‐10. The highest order species in the library is the tetrahedral [7]catenane.