Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems
Visible light induced photopolymerization: speeding up the rate of polymerization by using co-initiators in dye/amine photoinitiating systems
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DOI：
10.1016/s0032-3861(03)00286-6
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发表时间：
2003-06-01
期刊：
影响因子：
4.6
通讯作者：
Fouassier, JP
中科院分区：
文献类型：
--
作者：
Grotzinger, C;Burget, D;Fouassier, JP
对六种新设计的三组分体系（含染料、胺和三嗪衍生物）在可见光下引发多功能丙烯酸酯光聚合的活性进行了评价。染料的选择是基于热力学的考虑。对这些体系的光化学反应性的讨论揭示了热力学所起的作用，并概述了与动力学有关的不同方面。2003爱思唯尔科学有限公司版权所有。
The activity of six newly designed three-component systems (containing a dye, an amine and a triazine derivative) for the initiation of the photopolymerization of multifunctional acrylates under visible light has been evaluated. The selection of the dyes was based on thermodynamic considerations. A discussion of the photochemical reactivity of these systems reveals the role played by thermodynamics and outlines different aspects concerned with kinetics. (C) 2003 Elsevier Science Ltd. All rights reserved.