Recent Advances in Iron-Catalyzed Csp2-Csp2 Cross-Couplings
Recent Advances in Iron-Catalyzed Csp2-Csp2 Cross-Couplings
复制标题
DOI：
10.1055/s-0034-1380195
复制
发表时间：
2015-06-01
影响因子：
2.6
通讯作者：
Knochel, Paul
中科院分区：
文献类型：
--
作者：
Kuzmina, Olesya M.;Steib, Andreas K.;Knochel, Paul
本综述文章重点介绍了铁催化Csp（2）中心之间交叉偶联反应领域的最新进展。介绍了各种铁催化芳香族格氏试剂与不饱和卤化物偶联反应的反应范围，并对反应机理进行了探讨。1引言2历史工作3芳基有机金属化合物的铁催化的均偶联4铁催化的sp（2）-sp（2）交叉偶联4.1作为亲核试剂的芳基铜试剂4.2作为亲核试剂的芳基镁试剂4.2.1与烯基卤化物的偶联4.2.2与杂芳基卤化物的偶联4.2.3与芳基卤化物的偶联5结论
The present review article highlights recent progress in the field of iron-catalyzed cross-coupling reactions between Csp(2) centers. The reaction scope of various iron-catalyzed couplings between aromatic Grignard reagents and unsaturated halides is described and some mechanistic insights are given. 1 Introduction 2 Historical Work 3 Iron-Catalyzed Homocouplings of Aryl Organometallics 4 Iron-Catalyzed sp(2)-sp(2) Cross-Couplings 4.1 Arylcopper Reagents as Nucleophiles 4.2 Arylmagnesium Reagents as Nucleophiles 4.2.1 Couplings with Alkenyl Halides 4.2.2 Couplings with Heteroaryl Halides 4.2.3 Coupling with Aryl Halides 5 Conclusion