Kinetics of Three-compound Equilibrations. II. The Isomerization of Xylene1
Kinetics of Three-compound Equilibrations. II. The Isomerization of Xylene1
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三化合物平衡动力学。
DOI：
10.1021/ja01510a010
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发表时间：
1959
期刊：
影响因子：
--
通讯作者：
L. D. Yats
中科院分区：
文献类型：
--
作者：
R. Allen;T. Alfrey;L. D. Yats
目前文献报道烷基苯的异构化是通过分子内1，2-位移进行的。两个独立的研究表明二甲苯异构化的机理是分子内1，2-位移。2 '3 Schlatter提出了类似的机理，用于1，3-二甲基-2-异丙基苯异构化为1，3-二甲基-4-异丙基苯，4和分子内机理。
According to the literature at present, alkyl-benzenes isomerize by intramolecular 1, 2-shifts. Two independent studies indicate that the mech-anism for xylene isomerization is an intramolecular 1, 2-shift. 2'3 A similar mechanism has been pro-posed by Schlatter for the isomerizationof 1, 3-dimethyl-2-isopropylbenzene to l, 3-dimethyl-4-iso-propylbenzene, 4 and an intramolecular mechanism