Experimental and kinetic modeling study on 2,4,4-trimethy1-1-pentene ignition behind reflected shock waves
Experimental and kinetic modeling study on 2,4,4-trimethy1-1-pentene ignition behind reflected shock waves
复制标题
反射冲击波后2,4,4-三甲基1-1-戊烯点火的实验和动力学模拟研究
DOI：
10.1016/j.fuel.2017.01.055
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发表时间：
2017
期刊：
影响因子：
7.4
通讯作者：
Zuohua Huang
中科院分区：
文献类型：
--
作者：
Erjiang Hu;Geyuan Yin;Zhenhua Gao;Yang Liu;Jinfeng Ku;Zuohua Huang
Experiments of ignition delay times on 2,4,4-trimethyl-1-pentene were performed behind reflected shock waves at pressure ranging from 2 atm to 10 atm, at equivalence ratios from 0.5 to 2.0, and with fuel concentrations of 0.5%, 0.75% and 1%. All ignition delay times follow the Arrhenius rule, and discussions on the effect of pressure, temperature, equivalence ratio and fuel concentration on ignition delay times were made. Metcalfe model overpredicts the ignition reactivity of 2,4,4-trimethyl-1-pentene, and this model was modified to achieve better agreement for measured ignition delay times. Sensitivity analysis and reaction pathway analysis were conducted to gain a deep insight into 2,4,4-trimethyl-1-pentene ignition chemistry. The ignition delay time is sensitive to the small-radical reactions. In addition, H abstraction reactions and unimolecular decomposition reactions dominate the ignition process.
