Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed C¢X Bond Cleavage to Environmentally Benign Transition-Metal-Free C¢H Bond Activation.
Silylations of Arenes with Hydrosilanes: From Transition-Metal-Catalyzed C¢X Bond Cleavage to Environmentally Benign Transition-Metal-Free C¢H Bond Activation.
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DOI：
10.1002/cssc.201500467
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发表时间：
2015-07
期刊：
影响因子：
8.4
通讯作者：
Zheng Xu;Li‐Wen Xu
中科院分区：
文献类型：
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作者：
Zheng Xu;Li‐Wen Xu
碳-硅键的构建被认为是有机硅化学和绿色化学领域的一项激动人心的成就。这一领域的最新发展将使硅资源能够可持续地化学转化为合成有用的化合物。特别是在没有导向基团和氢受体的情况下，通过C-H键的活化来催化硅化反应是有机化学和绿色化学中最具挑战性的课题之一。这些关于催化硅化的非凡发现可以为在合成化学中更环保地利用地球上丰富的硅基资源铺平道路。
The construction of carbon-silicon bonds is highlighted as an exciting achievement in the field of organosilicon chemistry and green chemistry. Recent developments in this area will enable the sustainable chemical conversion of silicon resources into synthetically useful compounds. Especially, the catalytic silylation through C¢H bond activation without directing groups and hydrogen acceptors is one of the most challenging topics in organic chemistry and green chemistry. These remarkable findings on catalytic silylation can pave the way to a more environmentally benign utilization of earth-abundant silicon-based resources in synthetic chemistry.