Germylene and stannylene cleavage of Lawesson’s reagent

Germylene and stannylene cleavage of Lawesson’s reagent
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Lawesson 试剂的甲亚甲和亚锡裂解

DOI:
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发表时间:
1998
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通讯作者:
Brian G. Mcburnett
Brian G. Mcburnett
中科院分区:
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文献类型:
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作者:
C. Carmalt;Jason A. C. Clyburne;A. Cowley;Viviana Lomelí;Brian G. Mcburnett

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Lawesson试剂与双[双(三甲基硅基)氨基]锗(II)和双[双(三甲基硅基)氨基]锡(II)发生裂解反应,而与1,3-二叔丁基-1,3,2-二氮杂-2-叶立烯发生裂解反应,产物是一种新型的螺环锗衍生物。
Lawesson’s reagent undergoes cleavage reactions with bis[bis(trimethylsilyl)amino]germanium(II) and bis[bis(trimethylsilyl)amino]tin(II) whilst with 1,3-di-tert-butyl-1,3,2-diazagermol-2-ylidene the product is a novel spirocyclic germanium derivative.