Large and Small Solids: A Journey Through Inorganic Chemistry
Large and Small Solids: A Journey Through Inorganic Chemistry
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DOI：
10.1002/zaac.202200062
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发表时间：
2022-03
期刊：
影响因子：
--
通讯作者：
C. Feldmann
中科院分区：
文献类型：
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作者：
C. Feldmann
在庆祝ZAAC成立130周年之际，我们总结了20年来我们在无机化学领域的“大”固体（单晶化合物）和“小”固体（纳米材料）的历程。这包括合成（水、多元醇、醚、液氨、离子液体）和结构（晶体结构和纳米结构）以及各自的性质（特别是键合和稳定性、发光、催化和光催化、成像和给药）。大固体和小固体的具体例子包括金属氧化物纳米颗粒，贱金属纳米颗粒，空心纳米球，多卤化物和富卤素金属卤化物，羰基和簇状化合物，以及无机-有机混合纳米颗粒。
On the occasion to celebrate 130 years of ZAAC, we summarize about 20 years of our journey through inorganic chemistry with “large” solids (single-crystalline compounds) and “small” solids (nanomaterials). This includes the syntheses (water, polyols, ethers, liquid ammonia, ionic liquids) and structures (crystal structure and nanostructure) as well as the respective properties (especially bonding and stability, luminescence, catalysis and photocatalysis, imaging and drug delivery). Specific examples of large and small solids comprise metal-oxide nanoparticles, base-metal nanoparticles, hollow nanospheres, polyhalides and halogen-rich metal halides, carbonyl and cluster compounds, as well as inorganic-organic hybrid nanoparticles.