Synthesis of N‐Containing Heterocyclic Compounds Using Visible‐Light Photoredox Catalysis
Synthesis of N‐Containing Heterocyclic Compounds Using Visible‐Light Photoredox Catalysis
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DOI：
10.1002/chin.201616243
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发表时间：
2016-03
期刊：
影响因子：
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通讯作者：
Lei Zhou;M. Hossain;Tiebo Xiao
中科院分区：
文献类型：
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作者：
Lei Zhou;M. Hossain;Tiebo Xiao
氮杂环是一类非常重要的化合物，在材料科学、农业化学和药物化学中有着广泛的应用。因此，开发方便、高效和环境友好的合成方法来构建含氮杂环化合物一直是人们感兴趣的问题。由于可见光资源丰富，使用方便，在工业上有广阔的应用前景，在过去的几年里，利用可见光作为化学反应的驱动力受到了相当大的关注。根据形成的N-杂环的大小和类型，综述了近两年发表的可见光光氧化还原催化合成N-杂环的研究进展。在这一领域其他人的开创性著作的背景下，也提供了对作者贡献的简明总结。
Nitrogen heterocycles represent a highly important class of compounds which are widely used in materials science, agrochemistry, and medicinal chemistry. Therefore, there is continuing interest in the development of convenient, efficient, and environmentally benign synthetic methods for the construction of nitrogen containing heterocycles. Due to its natural abundance, ease of use, and promising application in industry, the use of visible light as a driving force for chemical reactions has received considerable attention in the past few years. This account summarizes the synthesis of N-heterocycles using visible-light photoredox catalysis published in the last two years, according to the size and type of the formed N-heterocyclic rings. In the context of seminal works of others in this area, a concise summary of the contributions of the authors is also offered.