Control of Major Carriers in an Ambipolar Polymer Semiconductor by Self-Assembled Monolayers
Control of Major Carriers in an Ambipolar Polymer Semiconductor by Self-Assembled Monolayers
复制标题
DOI：
10.1002/adma.201602893
复制
发表时间：
2017-01-04
影响因子：
29.4
通讯作者：
Takimiya, Kazuo
中科院分区：
文献类型：
--
作者：
Nakano, Masahiro;Osaka, Itaru;Takimiya, Kazuo
利用不同的自组装单分子膜，证明了双极性聚合物半导体PNDTI-BT的选择性单极化。对于p-单极化，1H，1H，2 H，2 H-全氟癸基三乙氧基硅烷是最有效的，而对于n-单极化，3-（N，N '-二甲氨基）-丙基三乙氧基硅烷是最好的。利用这些选择性单极化效应，互补逆变器的双极性聚合物的基础上，通过一个简单的溶液工艺制造的开关行为，大大改善了低功耗。
Selective unipolarization of an ambipolar polymer semiconductor, PNDTI-BT, by using different self-assembled monolayers, is demonstrated. For p-unipolarization, 1H,1H,2H,2H-perfluorodecyltriethoxy-silane is most effective, whereas for n-unipolarization, 3-(N,N'-dimethylamino)-propyltriethoxysilane is the best. Using these selective unipolarization effects, the complementary inverters based on the ambipolar polymer fabricated by a simple solution process show greatly improved switching behaviors with low power consumption.