Recent Advances in the Asymmetric Claisen Rearrangement Promoted by Chiral Organometallic Lewis Acids or Organic Bronsted-Lowry Acids
Recent Advances in the Asymmetric Claisen Rearrangement Promoted by Chiral Organometallic Lewis Acids or Organic Bronsted-Lowry Acids
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DOI：
10.2174/157017941206150828112854
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发表时间：
2015-01-01
影响因子：
1.8
通讯作者：
Lira Machado, Angelo Henrique
中科院分区：
文献类型：
--
作者：
Alves Fontoura Rodrigues, Tiago Costa;Silva, Wender Alves;Lira Machado, Angelo Henrique
Claisen重排反应是一种重要的C-C键形成反应，几十年来在重要化合物的合成中得到了广泛的应用。本文综述了2008年以来该重排反应的研究进展，讨论了手性有机金属刘易斯酸或有机Bronsted-Lowry酸催化的不对称Claisen重排反应的重要方面。
The Claisen rearrangement, an important C-C bond forming reaction, has been used enormously for many decades in the synthesis of important class of compounds. This review covers developments in this rearrangement since 2008, discusses important aspects about the asymmetric Claisen rearrangement catalyzed by chiral organometallic Lewis acids or organic Bronsted-Lowry acids.