A Supramolecular Polymer Blend Containing Two Different Supramolecular Polymers through Self-Sorting Organization of Two Heteroditopic Monomers
A Supramolecular Polymer Blend Containing Two Different Supramolecular Polymers through Self-Sorting Organization of Two Heteroditopic Monomers
复制标题
通过两种异二位单体的自排序组织含有两种不同超分子聚合物的超分子聚合物共混物
DOI：
10.1002/chem.201200016
复制
发表时间：
2012-04-01
影响因子：
4.3
通讯作者：
Huang, Feihe
中科院分区：
文献类型：
--
作者：
Dong, Shengyi;Yan, Xuzhou;Huang, Feihe
创造具有理想性质和新功能的复杂和高度有序结构是超分子化学和材料科学的基础，在药物输送系统、分子器件和光伏应用等高科技和生物相关领域起着至关重要的作用自然界，作为精确和高效的自组装过程的最好例子，促使化学家们通过利用非共价相互作用来开发高度有序的人工超分子组装，如超分子聚合物超分子聚合物通过可逆的高维相互作用（如主客体相互作用、氢键和金属配位）结合在一起，在过去二十年中已经成为最活跃的前沿之一，并受到了大量的关注与传统聚合物相比，超分子聚合物通常表现出许多动态或精确可控的特性，这些特性是由组成单体之间的动态连接引起的，并且具有作为自适应材料对环境作出反应的能力。近年来，人们对超分子聚合物的兴趣越来越大，不仅因为它们作为功能材料的潜在特性，而且因为它们有趣的结构和拓扑结构是潜在应用的一个基本方面不同聚合物的简单共混产生了性能可控、独特的新型高分子共混材料。聚合物共混物在高分子化学和材料科学中得到了广泛的研究[6,7]，而超分子聚合物共混物被定义为两种或两种以上不同且互斥的超分子的混合物
The creation of complex and highly-ordered structures with desired properties and novel functions has been fundamental to supramolecular chemistry and material science, and plays an essential role in high-tech and biorelated fields, such as drug delivery systems, molecular devices and photovoltaic applications.[1] Nature, as the best example of precise and efficient self-assembly processes, promotes chemists to engage in developing highly-ordered artificial supramolecular assemblies, such as supramolecular polymers through the utilization of noncovalent interactions.[2] Held together by reversible and highly dimensional interactions, such as host–guest interactions, hydrogen bonds, and metal coordination, supramolecular polymers have become one of the most active frontiers in the past two decades and have received a great deal of attention.[3] Compared with conventional polymers, supramolecular polymers typically show many dynamic or precisely controllable properties arising from dynamic linking between the constituent monomers and have the ability to respond to their environment as adaptive materials.[4]The interest in supramolecular polymers has expanded in recent years, not only for their potential properties as functional materials, but also for their intriguing architectures and topologies that act as a basic aspect of potential applications.[5] The simple blending of different polymers has produced new polymer blend materials with controllable and unique properties. Polymer blends have been widely studied in polymer chemistry and materials science,[6, 7] and as such supramolecular polymer blends, defined as mixtures of two or more different and mutually exclusive supramolecular