Toward chiral conductors: combining halogen bonding ability and chirality within a single tetrathiafulvalene molecule
Toward chiral conductors: combining halogen bonding ability and chirality within a single tetrathiafulvalene molecule
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DOI：
10.1039/c3ce40393a
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发表时间：
2013-01-01
期刊：
影响因子：
3.1
通讯作者：
Fourmigue, Marc
中科院分区：
文献类型：
--
作者：
Lieffrig, Julien;Le Pennec, Ronan;Fourmigue, Marc
手性和卤素键合能力结合在一个单一的四硫富瓦烯分子（1）与碘和二甲基（亚丙基二硫代）取代基，与I中心点中心点I相互作用发展沿着2（1）螺旋轴。手性混合价导电盐（1）（2）Cl具有强的一维电子结构。
Chirality and halogen bonding ability are combined in a single tetrathiafulvalene molecule (1) with iodo and dimethyl(propylenedithio) substituents, with I center dot center dot center dot I interactions developing along a 2(1) screw axis. The chiral mixed-valence conducting salt (1)(2)Cl exhibits a strongly 1D electronic structure.