Liquid Metals and Liquid Semiconductors
Liquid Metals and Liquid Semiconductors
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液态金属和液态半导体
DOI：
10.1002/anie.198005931
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发表时间：
1980
影响因子：
--
通讯作者：
F. Hensel
中科院分区：
文献类型：
--
作者：
F. Hensel
许多液体系统具有类似于晶体和非晶半导体的电学性质。这些液体中“半导体”行为的存在主要与从金属到“半导体”状态的连续转变有关，当热力学变量（如温度、密度或浓度）发生变化时。化学相互作用性质的变化和液体结构的相关变化对于过渡到“半导体”状态至关重要。这将在离子液体CsAu、共价液体硒和膨胀液态金属中得到证明。
Numerous liquid systems have electrical properties which resemble those of crystalline and amorphous semiconductors. The existence of “semiconducting” behavior in these liquids is mostly related to a continuous transition from a metallic to a “semiconducting” state when a thermodynamic variable such as temperature, density or concentration is changed. Changes in the nature of the chemical interaction and the associated changes in the structure of the liquid are of fundamental importance for the transition to a “semiconducting” state. This will be demonstrated for the ionic liquid CsAu, for covalent liquid selenium, and for expanded liquid metals.