Characterization of Rhus vernicifera and Rhus succedanea lacquer films and their pyrolysis mechanisms studied using two-stage pyrolysis gas chromatography mass spectrometry
Characterization of Rhus vernicifera and Rhus succedanea lacquer films and their pyrolysis mechanisms studied using two-stage pyrolysis gas chromatography mass spectrometry
复制标题
DOI：
10.1016/0165-2370(96)00945-x
复制
发表时间：
1996-09-01
影响因子：
6
通讯作者：
Higuchi, T
中科院分区：
文献类型：
--
作者：
Niimura, N;Miyakoshi, T;Higuchi, T
使用两级热解-气相色谱/质谱 (Py-GC/MS) 对日本用作木材、瓷器和金属制品表面涂层的漆树和漆树漆进行了研究。通过在 400 摄氏度下热解，在每个漆膜中检测到漆酚和漆酚成分。这些是单体，是漆树和漆树漆膜的特征。此外，在400℃热解后，通过500℃热解检测到烯烃、烷烃、烯基酚和烷基酚。基于这些结果，考虑了各漆膜的热解机理。热解产物来自漆酚和漆醇聚合物。这些热解产物清楚地反映了每个漆膜的结构。
Rhus vernicifera and Rhus succedanea lacquers, which are used as a surface coating for wood, porcelain and metalware in Japan, were investigated using two-stage pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). Urushiol and laccol components were detected in each lacquer film by pyrolysis at 400 degrees C. These are the monomers, and are characteristic of Rhus vernicifera and Rhus succedanea lacquer films. In addition, alkenes, alkanes, alkenylphenols and alkylphenols were detected by pyrolysis at 500 degrees C after pyrolysis at 400 degrees C. Based on these results, the pyrolysis mechanisms of the respective lacquer films were considered. The pyrolysis products were from the urushiol and laccol polymers. These pyrolysis products clearly reflect the structure of each lacquer film.