Catalytic Activities of a Bis(carbene)-Derived Nickel(II)-Pincer Complex in Kumada-Tamao-Corriu and Suzuki-Miyaura Coupling Reactions for the Synthesis of Biaryl Compounds
Catalytic Activities of a Bis(carbene)-Derived Nickel(II)-Pincer Complex in Kumada-Tamao-Corriu and Suzuki-Miyaura Coupling Reactions for the Synthesis of Biaryl Compounds
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DOI：
10.1055/s-2007-983845
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发表时间：
2007-09
期刊：
影响因子：
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通讯作者：
K. Inamoto;J. Kuroda;T. Sakamoto*;K. Hiroya
中科院分区：
文献类型：
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作者：
K. Inamoto;J. Kuroda;T. Sakamoto*;K. Hiroya
研究了钳形双咪唑-2-二吡啶镍配合物的催化活性。该配合物在熊田- tamao - corriu和铃木- miyaura偶联反应中是一种有效的催化剂，广泛的芳基-X （X = Br， Cl和F）化合物的偶联反应，提供多种联芳基化合物，通常收率较高。
The catalytic activities of a pincer type bis(imidazolin-2-ylidene)nickel(II) complex were evaluated. The complex was found to be an effective catalyst in the Kumada-Tamao-Corriu and Suzuki-Miyaura coupling reactions of a broad range of aryl-X (X = Br, Cl and F) compounds, providing a variety of biaryl compounds, generally in good yield.