Potentials and Limitations of Automated Parallel Emulsion Polymerization

Potentials and Limitations of Automated Parallel Emulsion Polymerization
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自动化平行乳液聚合的潜力和局限性

DOI:
10.1002/marc.200390050
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发表时间:
2003
影响因子:
4.6
通讯作者:
A. Herk
A. Herk
中科院分区:
化学3区
文献类型:
--
作者:
D. Voorn;M. M. Fijten;J. Meuldijk;U. Schubert;A. Herk

文献摘要

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自动化并联合成机器人在聚合过程研究中的应用是目前的主要兴趣。本文介绍了苯乙烯和醋酸乙烯酯乳液聚合的应用。详细研究了乳液和胶乳的制备,并与传统的搅拌釜反应器进行了比较。特别是涡流混合的影响,以及关于固体含量和反应器结垢的限制得到解决。
The application of automated parallel synthesizer robots for the investigation of polymerization processes is of major interest at present. In this contribution we describe the application of the emulsion polymerization of styrene and vinyl acetate. The preparations of emulsions and latexes were investigated in detail and compared to conventional stirred tank reactors. In particular the influence of the vortex mixing as well as the limitations regarding solid content and reactor fouling are addressed.