Thermochemistry of silicon-containing compounds. Part 1.—Silicon–halogen compounds, an evaluation
Thermochemistry of silicon-containing compounds. Part 1.—Silicon–halogen compounds, an evaluation
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含硅化合物的热化学。第 1 部分——硅-卤素化合物，评估
DOI：
10.1039/f19837902233
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发表时间：
1983
期刊：
影响因子：
--
通讯作者：
R. Walsh
中科院分区：
文献类型：
--
作者：
R. Walsh
Literature data on the heats of formation of silicon–halogen compounds have been collected and reviewed. The coverage includes all tetravalent monosilicon compounds containing Si—H—X, where X is a single halogen, as well as the subhalides SiXn, where n= 1, 2 or 3. The data are critically evaluated from the standpoints of bond additivity and general chemical reactivity of the species involved as well as by detailed consideration of individual studies. Earlier compilations or reviews are discussed. A set of recommended values (with uncertainties) is proposed. For the divalent species, SiX2, a self-consistent set of lone-pair stabilisation energies is obtained.
