Simple Synthesis of a Chlorin - Fullerene Dyad with a Novel Ring-Closure Reaction.

Simple Synthesis of a Chlorin - Fullerene Dyad with a Novel Ring-Closure Reaction.
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DOI:
10.1002/(sici)1521-3773(20000204)39:3
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发表时间:
2000-02
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影响因子:
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通讯作者:
Montforts;Kutzki
Montforts;Kutzki
中科院分区:
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文献类型:
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作者:
Montforts;Kutzki

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为了模拟光合作用反应中心,二氢卟酚-富勒烯二元体1是由线性四吡咯和C(60)在一锅反应中合成的。它是第一个含有富勒烯和二氢卟酚单元的二联体,二氢卟酚单元是自然发生的光合系统的发色团。
To model the photosynthetic reaction center, the chlorin - fullerene dyad 1 was synthesized in a one-pot reaction from a linear tetrapyrrole and C(60). It is the first dyad of this type which contains a fullerene and a chlorin unit, the chromophore of naturally occurring photosynthetic systems.