A Cycloaddition–Cyclodehydrogenation Route from Stilbenoids to Extended Aromatic Hydrocarbons
A Cycloaddition–Cyclodehydrogenation Route from Stilbenoids to Extended Aromatic Hydrocarbons
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茋类化合物环加成-环脱氢合成扩展芳烃路线
DOI：
10.1002/anie.199515831
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发表时间：
1995
影响因子：
--
通讯作者：
K. Müllen
中科院分区：
文献类型：
--
作者：
Markus Müller;Heike Mauermann‐Düll;M. Wagner;V. Enkelmann;K. Müllen
平面石墨碎片的非常规途径已被证明与芳香族多环化合物的新合成，如2。1的分子内Diels-Alder反应后进行芳构化和氧化偶联得到2（C30 H16）。C54 H22聚芳烃的类似合成表明，这种方法可以用来制备更大的石墨截面。
An unconventional route to planar graphitic fragments has been demonstrated with the novel synthesis of aromatic polycycles such as 2. The intramolecular Diels–Alder reaction of 1 is followed by aromatization and oxidative aryl–aryl coupling to afford 2 (C 30 H 16) in high yield. The analogous synthesis of a C 54 H 22 polyarene shows that this approach can be used to prepare larger graphitic sections.