THERMODYNAMICS OF ELECTROLYTES - BINARY-MIXTURES FORMED FROM AQUEOUS NACL, NA2SO4, CUCL2, AND CUSO4 AT 25DEGREESC
THERMODYNAMICS OF ELECTROLYTES - BINARY-MIXTURES FORMED FROM AQUEOUS NACL, NA2SO4, CUCL2, AND CUSO4 AT 25DEGREESC
复制标题
DOI：
10.1007/bf00646413
复制
发表时间：
1976-01-01
影响因子：
1.2
通讯作者：
PITZER, KS
中科院分区：
文献类型：
--
作者：
DOWNES, CJ;PITZER, KS
高离子强度下的渗透系数在NaCl、Na 2SO 4、CuCl 2和CuSO 4形成的二元混合物中有五种被报道;第六种被研究的体系NaCl− Na 2SO 4是由吴、拉什和斯卡查德研究的。Pitzer最近发展的方程成功地用于解释实验结果。给出了纯CuSO 4和CuCl 2溶液的活度和渗透系数的修正值。
Osmotic coefficients to high ionic strengths are reported for five of the binary mixtures formed from NaCl, Na2SO4, CuCl2, and CuSO4; the sixth system studied, NaCl−Na2SO4, is one studied by Wu, Rush, and Scatchard. The equations recently developed by Pitzer are used successfully in the interpretation of the experimental results. Revised values are given for the activity and osmotic coefficients for pure CuSO4and CuCl2solutions.