Bifurcation of self-motion depending on the reaction order
Bifurcation of self-motion depending on the reaction order
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根据反应顺序的自运动分叉
DOI：
10.1039/b815677h
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发表时间：
2009
影响因子：
3.3
通讯作者：
M. Murakami and S. Nakata
中科院分区：
文献类型：
--
作者：
M.Nagayama;M.Yadome;N.Kato;J.Kirisaka;M. Murakami and S. Nakata
作为一个简单的例子，一个自主电机的自运动耦合的酸碱反应的特性进行了数值模拟和实验研究在空气/水界面。振荡和均匀运动被归类为一个函数的反应级数的数值计算，使用的数学模型，结合了从材料颗粒的驱动力和酸碱反应的动力学的表面活性层的分布。实验观察到的性质的自运动的船粘附到樟脑衍生物与单或二羧酸的磷酸盐水相作为基地。
As a simple example of an autonomous motor, the characteristic features of self-motion coupled with the acid–base reaction were numerically and experimentally investigated at the air/aqueous interface. Oscillatory and uniform motion were categorized as a function of the reaction order by numerical computations using a mathematical model that incorporates both the distribution of the surface active layer developed from a material particle as the driving force and the kinetics of the acid–base reaction. The nature of the self-motion was experimentally observed for a boat adhered to a camphor derivative with a mono- or di-carboxylic acid on a phosphate aqueous phase as the base.