Statistical Thermodynamics of Associated Polymer Solutions
Statistical Thermodynamics of Associated Polymer Solutions
复制标题
相关聚合物溶液的统计热力学
DOI：
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发表时间：
1991
期刊：
影响因子：
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通讯作者：
I. Sanchez
中科院分区：
文献类型：
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作者：
C. Panayiotou;I. Sanchez
对聚合物溶液的晶格流体理论进行了修改，以考虑聚合物和溶剂之间的强相互作用（氢键）。所得到的模型是一个状态方程，能够描述这些系统的热力学性质的扩展范围内的外部条件从普通的液体状态的临界或超临界状态。一般情况下，处理溶剂自缔合和交叉缔合与聚合物。
The lattice-fluid theory for polymer solutions was modified to account for strong interactions (hydrogen bonding) between the polymer and solvent. The resultant model is an equation-of-state able to describe thermodynamic properties of these systems over an extended range of external conditions from the ordinary liquid state up to the critical or supercritical state. The general case is treated where the solvent self-associates and cross-associates with the polymer.