Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction
Order-to-disorder structural transformation of a coordination polymer and its influence on proton conduction
复制标题
DOI：
10.1039/c4cc04370g
复制
发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Kitagawa, Susumu
中科院分区：
文献类型：
--
作者：
Horike, Satoshi;Chen, Wenqian;Kitagawa, Susumu
我们观察到了Cu2+配位聚合物中从有序到无序的结构转变，并研究了它对质子电导的影响。这种转变在结构中产生了高流动性的质子载体。该材料在130℃时的电导率大于10(-2)S cm(-1)。用EXAFS、TPD-MS和核磁共振研究了其结构转变和导电机理。
We observed an ordered-to-disordered structural transformation in a Cu2+ coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 degrees C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.