Synthesis of Cyclic Allylborates from 1,3-Dienes and a Diboron Reagent
Synthesis of Cyclic Allylborates from 1,3-Dienes and a Diboron Reagent
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由 1,3-二烯和二硼试剂合成环状烯丙基硼酸酯
DOI：
10.1002/anie.202202226
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发表时间：
2022
期刊：
影响因子：
--
通讯作者：
T. Fujihara
中科院分区：
文献类型：
--
作者：
S. Sakuragi;T. Akiba;T. Tanahashi;T. Fujihara
环状烯丙基硼酸酯的合成是通过 1,3-二烯和 B2pin2 在铜催化剂下反应实现的。几种 1,3-二烯以中等到高产率转化为相应的环状烯丙基硼酸酯。获得的环状烯丙基硼酸酯可用于多种有机转化，例如亲电子试剂的烯丙基化和铃木-宫浦偶联。
The synthesis of cyclic allylborates was achieved by the reaction of 1,3‐dienes and B2pin2using a copper catalyst. Several 1,3‐dienes were converted to the corresponding cyclic allylborates in moderate to high yields. The cyclic allylborate obtained could be used in several organic transformations such as allylation of electrophiles and Suzuki–Miyaura coupling.