THE ENTHALPIES OF FORMATION OF ZIRCONIUM DIHYDRIDE AND ZIRCONIUM DIDEUTERIDE
THE ENTHALPIES OF FORMATION OF ZIRCONIUM DIHYDRIDE AND ZIRCONIUM DIDEUTERIDE
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DOI：
10.1021/j100801a025
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发表时间：
1963-07
期刊：
影响因子：
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通讯作者：
D. Fredrickson;R. L. Nuttall;H. Flotow;W. Hubbard
中科院分区：
文献类型：
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作者：
D. Fredrickson;R. L. Nuttall;H. Flotow;W. Hubbard
用精密氧弹量热法测定了ZrH_2和ZrD_2的标准燃烧能。测定的AEJ值为-290.03 ±0.24 kcal。mole-1的ZrH 2和-290.80 ±0.18 kcal。mole-1的ZrD 2。在298.15 K。生成焓Δ H，0和生成吉布斯自由能Δ G为-38.90 ± 0.31kcal。摩尔-1和-29.32 ±0.31千卡。mole ~（-1），ZrH_2为-40.22 ±0.27千卡。摩尔-1和-29.86 ±0.27千卡。mole-1，对于ZrD 2。
The standard energies of combustion of ZrH2 and ZrD2 were determined by precisionoxygen bomb calorime-try. The values found for AEJ were-290.03±0.24 kcal. mole" 1 of ZrH2 and-290.80±0.18 kcal. mole" 1 of ZrD2. At 298.15 K. the enthalpy of formation, AH, 0, and the Gibbs energy offormation, AG¡, were cal-culated to be— 38.90±0.31 kcal. mole” 1 and—29.32±0.31 kcal. mole" 1, respectively, for ZrH2, and— 40.22±0.27 kcal. mole” 1 and—29.86±0.27 kcal. mole" 1, respectively, for ZrD2.