Ugibohlin:: A new dibromo-seco-isophakellin from Axinella carteri

Ugibohlin:: A new dibromo-seco-isophakellin from Axinella carteri
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DOI:
10.1021/np010202o
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发表时间:
2001-12-01
影响因子:
5.1
通讯作者:
Likos, J
Likos, J
中科院分区:
生物学2区
文献类型:
--
作者:
Goetz, GH;Harrigan, GG;Likos, J

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对菲律宾塔拉卡宁岛芦苇坡采集的海绵Axinella carteri进行化学研究,发现了新的代谢物ugibohlin(1)及其已知的环状衍生物二溴异珊瑚蛋白(2)。利用高场2D核磁共振波谱(包括H-1-H-1 COSY、HSQC和HMBC)对分离的代谢物进行结构鉴定。修改后的化学位移作业提供给2。
Chemical investigation of a marine sponge, Axinella carteri, collected on a reed slope of Talakanen Island, Phillipines, has afforded the new metabolite ugibohlin (1), along with its known cyclic derivative dibromoisophakellin (2). Structure elucidation of the isolated metabolites involved high-field 2D NMR spectroscopy including H-1-H-1 COSY, HSQC, and HMBC. Revised chemical shift assignments are provided for 2.